Proceedings of the 42nd International Conference on Advanced Ceramics and Composites

Ceramic Engineering and Science Proceedings Volume 39, Issue 2

A Collection of Papers Presented at the 42nd International Conference on Advanced Ceramics and Composites January 21-26, 2018, Daytona Beach, Florida

Edited by

Jonathan Salem

Dietmar Koch

Peter Mechnich

Mihails Kusnezoff

Narottam Bansal

Jerry LaSalvia

Palani Balaya

Zhengyi Fu

Tatsuki Ohji

Volume Editors

Valerie Wiesner

Manabu Fukushima

This edition first published 2019
© 2019 The American Ceramic Society

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The rights of Jonathan Salem, Dietmar Koch, Peter Mechnich, Mihails Kusnezoff, Narottam Bansal, Jerry LaSalvia, Palani Balaya, Zhengyi Fu and Tatsuki Ohji to be identified as the authors of the editorial material in this work have been asserted in accordance with law

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Library of Congress Cataloging-in-Publication Data is available.

ISBN: 9781119543268
ISSN: 1042-1122

Cover design by Wiley

CONTENTS

COVER

TITLEPAGE

INTRODUCTION

MECHANICAL BEHAVIOR AND PERFORMANCE OF CERAMICS AND COMPOSITES

FRACTURE TOUGHNESS OF MODERN AND ANCIENT GLASSES AND GLASS CERAMICS AS MEASURED BY THE SEPB METHOD
1. ABSTRACT
2. INTRODUCTION
3. MATERIALS
4. EXPERIMENTAL PROCEEDURE
5. RESULTS AND DISCUSSION
6. CONCLUSIONS
7. ACKNOWLEDGEMENTS
8. REFERENCES
EROSION BEHAVIOR IN A GAS TURBINE GRADE OXIDE/OXIDE CERAMIC MATRIX COMPOSITE
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENTAL PROCEDURE
4. RESULTS AND DISCUSSION
5. CONCLUSIONS
6. ACKNOWLEDGMENT
7. REFERENCES
APPLYING ASTM INTERNATIONAL C1421 TO GLASSES AND OPTICAL CERAMICS
1. SUMMARY
2. INTRODUCTION
3. COMPLICATIONS IN FRACTURE TOUGHNESS TESTING
4. SUMMARY
5. REFERENCES
EFFECT OF CONTROL MODE AND TEST RATE ON THE MEASURED FRACTURE TOUGHNESS OF ADVANCED CERAMICS
1. ABSTRACT
2. NOMENCLATURE
3. INTRODUCTION
4. PROCEDURE
5. RESULTS
6. CONCLUSIONS
7. APPENDIX: LINEAR CORRELATION OF CMOD AND BACK FACE STRAIN
8. ACKNOWLEDGMENTS
9. REFERENCES
IN-SITU STUDY ON SiC-Si INTERFACIAL BONDING STRENGTH OF REACTION BONDED SiC/Si COMPOSITES
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENTAL METHODS
4. RESULTS AND DISCUSSION
5. CONCLUSION
6. ACKNOWLEDGMENTS
7. REFERENCE
EVALUATION OF NEW TECHNIQUE TO ESTIMATE YIELD STRESS IN BRITTLE MATERIALS VIA SPHERICAL INDENTATION TESTING
1. ABSTRACT
2. INTRODUCTION
3. DEVELOPMENT OF NEW TECHNIQUE
4. MATERIALS AND EXPERIMENTAL METHODS
5. RESULTS AND DISCUSSION
6. CONCLUSIONS
7. ACKNOWLEDGMENTS
8. REFERENCES

ADVANCED CERAMIC COATINGS FOR STRUCTURAL, ENVIRONMENTAL, AND FUNCTIONAL APPLICATIONS

OXIDATION STUDY OF AN ULTRA HIGH TEMPERATURE CERAMIC COATING BASED ON HFSiCN
1. ABSTRACT
2. 1. INTRODUCTION
3. 2. EXPERIMENTAL
4. 3. RESULTS AND DISCUSSION
5. 4. CONCLUSION
6. AKNOWLEGEMENTS
7. REFERENCES

15^TH INTERNATIONAL SYMPOSIUM ON SOLID OXIDE FUEL CELLS (SOFC): MATERIALS, SCIENCE, AND TECHNOLOGY

INVESTIGATION OF (La_1-X,Ca_X)(Ni_0.25Fe_0.25Cr_0.25Co_0.25)O₃ FOR SOLID OXIDE FUEL CELLS CATHODE MATERIALS
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENTAL METHOD
4. RESULTS AND DISCUSSION
5. CONCLUSIONS
6. REFERENCES
DEVELOPMENT OF CATHODE CONTACTING FOR SOFC STACKS
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENTAL
4. RESULTS AND DISCUSSION
5. CONCLUSIONS
6. ACKNOWLEDGEMENTS
7. REFERENCES
MICROSTRUCTURE MODIFICATION IN THE ELECTRODES TO ENHANCE PERFORMANCE OF THE ANODE-SUPPORTED SOLID OXIDE FUEL CELL
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENTAL DETAILS
4. RESULTS AND DISSCUSION
5. CONCLUSIONS
6. REFERENCES
PREPARATION AND CHARACTERIZATION OF BaY_0.2Ce_0.7Zr_0.1O_3−δ CERAMIC POWDER BY GLYCINE NITRATE COMBUSTION (GNC) PROCESS FOR PROTON-CONDUCTING SOLID OXIDE FUEL CELL
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENTAL
4. RESULTS AND DISSCUSION
5. CONCLUSION
6. ACKNOWLEDGEMENT
7. REFERENCES
EFFECTS OF COMPOSITE RATIO OF VERMICULITE/TALC SEAL MATERIAL ON GAS LEAK PROPERTIES
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENTAL
4. RESULTS AND DISCUSSION
5. CONCLUSIONS
6. REFERENCES
PERFORMANCE TEST FOR ANODE-SUPPORTED AND METAL-SUPPORTED SOLID OXIDE ELECTROLYSIS CELL UNDER DIFFERENT CURRENT DENSITIES
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENTAL
4. RESULTS AND DISSCUSION
5. CONCLUSIONS
6. ACKNOWLEDGMENT
7. REFERENCES
PROTECTIVE COATINGS FOR SOFC METALLIC INTERCONNECTS
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENTAL
4. RESULTS AND DISCUSSION
5. CONCLUSIONS
6. ACKNOWLEDGEMENTS
7. REFERENCES
DEVELOPMENT OF PORTABLE SOLID OXIDE FUEL CELL SYSTEM DRIVEN BY HYDROCARBON AND ALCOHOL FUELS
1. ABSTRACT
2. INTRODUCTION
3. THE FIRST PROTOTYPE PORTABLE SOFC SYSTEM
4. TECHNOLOGY DEVELOPMENT OF PORTABLE ELECTRICITY GENERATOR USING MICRO SOFC SUPPORTED BY NEDO
5. THE SECOND PROTOTYPE PORTABLE SOFC SYSTEM
6. ACKNOWLEDGEMENT
7. REFERENCES
PHASE FIELD MODELLING OF MICROSTRUCTURAL CHANGES IN NI/YSZ SOLID OXIDE ELECTROLYSIS CELL ELECTRODES
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENTAL
4. PHASE FIELD MODEL FORMULATION
5. RESULTS
6. DISCUSSION
7. CONCLUSIONS
8. ACKNOWLEDGEMENTS
9. REFERENCES
DEVELOPMENT OF Fe/Cr ALLOY-SUPPORTED SOLID OXIDE FUEL CELL BY PLASMA TECHNIQUE
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENTAL
4. RESULTS AND DISCUSSION
5. CONCLUSION
6. REFERENCES

Armor Ceramics: Challenges and New Developments

EFFECTS OF HARDNESS AND TOUGHNESS OF CERAMIC IN A CERAMIC ARMOUR MODULE AGAINST LONG ROD IMPACTS
1. ABSTRACT
2. INTRODUCTION
3. MATERIALS AND TEST METHODS
4. EXPERIMENTAL RESULTS
5. SIMULATION
6. CONCLUSION
7. REFERENCES
MESOSCALE SIMULATIONS OF BORON CARBIDE SUBJECTED TO SHOCKWAVE PROPAGATION
1. ABSTRACT
2. INTRODUCTION
3. MATERIALS AND METHODS
4. RESULTS AND DISCUSSION
5. CONCLUSIONS
6. ACKNOWLEDGEMENTS
7. REFERENCES
FIRST PRINCIPLES MODEL OF YTTRIUM ADSORPTION ON BORON SUBOXIDE (0001) SURFACE
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENTAL METHOD
4. COMPUTATIONAL METHOD
5. RESULTS AND DISCUSSION
6. SUMMARY AND CONCLUSIONS
7. ACKNOWLEDGEMENTS
8. REFERENCES
GENERATION OF POLYCRYSTALLINE MICROSTRUCTURES FOR THE DISCRETIZATION ON-THE-FLY OF FE MODELS FOR MULTI-SCALE SIMULATIONS
1. ABSTRACT
2. INTRODUCTION
3. VORONOI-BASED TESSELLATION TECHNIQUES
4. REPRESENTATIVE MODELS OF POLYCRYSTALLINE MICROSTRUCTURES
5. APPLICATION TO MULTISCALE SIMULATIONS
6. CONCLUSIONS
7. ACKNOWLEDGEMENTS
8. REFERENCES

Advanced Materials and Technologies for Direct Thermal Energy Conversion and Rechargeable Energy Storage

THE TAPE-CASTING AND PAS SINTERING OF LLZO CERAMIC MEMBRANE ELECTROLYTE
1. ABSTRACT
2. KEYWORDS
3. INTRODUCTION
4. EXPERIMENTAL SECTION
5. RESULTS AND DISCUSSIONS
6. CONCLUSION
7. ACKNOWLEDGMENTS
8. REFERENCES

12^th International Symposium on Advanced Processing & Manufacturing Technologies for Structural & Multifunctional Materials and Systems

THERMAL EXPANSION COEFFICIENT CONTROLLED Cu-ZrW_2-xMo_xO₈ CERMET MATERIAL PREPARED USING SPARK PLASMA SINTERING
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENT
4. RESULTS
5. CONCLUSION
6. REFERENCES
INFLUENCES OF LASER CONDITION AND SLIT SHAPE ON JOINABILITY OF ZIRCALOY-SiC/SiC COMPOSITE TUBE JOINT
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENTAL PROCEDURE
4. EFFECT OF CUTTING METHODS
5. EFFECT OF SLIT SHAPE
6. CONCLUSIONS
7. REFERENCES
ELECTROCONDUCTIVE OXIDE CERAMICS WITH GRAPHENE-ENCAPSULATED FILLERS
1. ABSTRACT
2. INTRODUCTION
3. EXPERIMENTAL
4. RESULTS AND DISCUSSION
5. CONCLUSIONS
6. ACKNOWLEDGEMENTS
7. REFERENCES

Eula

List of Illustration

Chapter 1

Figure 1 Pieces from the Jalame excavation. Three green cullet pieces are...
Figure 2 SEPB precracks in the Jalame glass with the precracks marked. (a)...
Figure 3 SEPB precracks in two glass ceramics. (a) shows the LAS form whi...
Figure 4 Individual K_Ic outcomes for five soda lime sil...

Chapter 2

Figure 1 Examples of erosion damage encountered by hot-section components....
Figure 2 Typical microstructure of N720/alumina oxide/oxide CMC used in...
Figure 3 Schematic of erosion testing rig.
Figure 4 (a) Experimental setup for erosion testing: (i) full support c...
Figure 5 SEM images and particle distribution analysis of glass beads.
Figure 6 Summary of erosion damage morphology generated in N720/alumina...
Figure 7 Cross-sectional image of erosion damage of the N720/alumina ox...
Figure 8 Erosion rate as a function of (a) particle velocity and (b) pa...
Figure 9 Schematic highlighting the formation of lateral cracks during ...
Figure 10 Typical load versus displacement curves determined from N720/...
Figure 11 Post-erosion flexural strength as a function of particle velo...
Figure 12 Post-erosion flexural strength versus crater depth (crack siz...

Chapter 3

Figure 1 ASTM C1421 test method configurations.
Figure 2 Fracture toughness of silicon nitrides as measured via two sta...
Figure 3 Water causing bond breakage in a silicate.
Figure 4 Fracture toughness K_Isc as a function of str...
Figure 5 Slow crack growth curve for soda-lime silicate glass with supe...
Figure 6 (a) and (b) Precracks in a chevron notch; (c) scribe; and (d) ...
Figure 7 Effect of a severe crack on the compliance of a chevron-notche...
Figure 8 Precracked spinel SEPB specimen and (b) post-fracture surface...
Figure 9 Examples of SCF precracks in a coarse grained AlON: (a) well d...
Figure 10 (a) Schematic and (b) picture of the double torsion configura...
Figure 11 (a) Fracture resistance of ZnSe as measured with specimen con...
Figure 12 Crack growth resistance of alumina along with standard fractu...

Chapter 21

Figure 1: Position of the cell boundary (dashed line) with the classic (...
Figure 2: Graphical illustration of the angles η and μ in ...
Figure 3: Sample Voronoi tessellation (left) and underlying sphere condi...
Figure 4: Cross-sectional grain size distribution of alumina microstruct...
Figure 5: Sample tessellation (left) and relative discretisation (right)

Chapter 22

Figure 1 (A) Photograph, (B) SEM image, (C) and (D) EDS images of the gre...
Figure 2 TG-TDA curve of LLZO green film
Figure 3 XRD pattern of LLZO ceramic membranes
Figure 4 SEM images of LLZO ceramic membranes sintered at (A) 1100 °...
Figure 5 EIS at room temperature of LLZO ceramic membrane sintered at dif...

Chapter 23

Figure 1 XRD patterns of Cu-ZrW₂O₈ and Cu-ZrWMoO...
Figure 2 SEM-EDX results of Cu-ZrW_2-xMo_xO₈...
Figure 3 TMA curves of Cu-ZrW₂O₈ and Cu-ZrWMoO 8 co...
Figure 4 Thermal conductivity of Cu-ZrW₂O₈ composit...

Chapter 24

Figure 1 Photographs of SiC/SiC composite tubes.
Figure 2 Photograph of zircaloy and SiC/SiC composite tubes with titani...
Figure 3 Schematic illustration of slit shape.
Figure 4 Beam profile of diode laser of flat-top beam¹⁸.
Figure 5 Photographs of experimental equipment for laser irradiation.
Figure 6 Photograph of zircaloy - SiC/SiC composite joints after...
Figure 7 SEM images of joint interface of zircaloy - SiC/ SiC composite...
Figure 8 BEI and EDS results of adhesion part between zircaloy and SiC/...
Figure 9 SEM images of joint interface of zircaloy - SiC/ SiC composite...
Figure 10 BEI of adhesion part between zircaloy and SiC/SiC composite w...
Figure 11 Photograph of zircaloy - SiC/SiC composite joints with hook s...
Figure 12 SEM images of joint interface of zircaloy - SiC/ SiC composit...
Figure 13 BEI and EDS results of adhesion part between zircaloy and SiC...

Chapter 25

Figure 1 SEM images of the mullite fibers array (a, b), TEM image of th...
Figure 2 Schematic representation of the processing rout (a), and schem...

INTRODUCTION

This collected proceedings consists of 25 papers that were submitted and approved for the proceedings of the 42nd International Conference on Advanced Ceramics and Composites (ICACC), held January 21-26, 2018 in Daytona Beach, Florida. ICACC is the most prominent international meeting in the area of advanced structural, functional, and nanoscopic ceramics, composites, and other emerging ceramic materials and technologies. This prestigious conference has been organized by the Engineering Ceramics Division (ECD) of The American Ceramic Society (ACerS) since 1977.

The 42^nd ICACC hosted over 950 attendees from 37 countries. The topics ranged from ceramic nanomaterials to structural reliability of ceramic components, which demonstrated the linkage between materials science developments at the atomic level and macro level structural applications. Papers addressed material, model, and component development and investigated the interrelations between the processing, properties, and microstructure of ceramic materials. This year's conference included a special symposium in honor of Dr. Mrityunjay Singh titled: Advancing Frontiers of Ceramics for Sustainable Societal Development.

The 2018 conference was organized into the following 17 symposia, 3 Focused Sessions and 2 Special Symposia:

Symposium 1	Mechanical Behavior and Performance of Ceramics and Composites
Symposium 2	Advanced Ceramic Coatings for Structural, Environmental, and Functional Applications
Symposium 3	15 th International Symposium on Solid Oxide Fuel Cells (SOFC): Materials, Science, and Technology
Symposium 4	Armor Ceramics: Challenges and New Developments
Symposium 5	Next Generation Bioceramics and Biocomposites
Symposium 6	Advanced Materials and Technologies for Direct Thermal Energy Conversion and Rechargeable Energy Storage
Symposium 7	12th International Symposium on Nanostructured Materials: Functional Nanomaterials and Thin Films for Sustainable Energy Harvesting, Environmental and Health Applications
Symposium 8	12^th International Symposium on Advanced Processing & Manufacturing Technologies for Structural & Multifunctional Materials and Systems
Symposium 9	Porous Ceramics: Novel Developments and Applications
Symposium 10	Virtual Materials (Computational) Design and Ceramic Genome
Symposium 11	Advanced Materials and Innovative Processing ideas for the Production Root Technology
Symposium 12	Materials for Extreme Environments: Ultrahigh Temperature Ceramics (UHTCs) and Nano-laminated Ternary Carbides and Nitrides (MAX Phases)
Symposium 13	Advanced Ceramics and Composites for Nuclear Fission and Fusion Energy
Symposium 14	Crystalline Materials for Electrical, Optical and Medical Applications
Symposium 15	Additive Manufacturing and 3D Printing Technologies
Symposium 16	Geopolymers, Chemically Bonded Ceramics, Eco-friendly and Sustainable Materials
Symposium 17	Advanced Ceramic Materials and Processing for Photonics and Energy
Focused Session 1	Bio-Inspired Processing of Advanced Materials
Focused Session 2	Tomography and Microscopy Based Modeling of Ceramics
Focused Session 3	Chemical Processing of Functional Materials
Special Symposia	7th Global Young Investigators Forum (GYIF)
Special Symposia	Advancing Frontiers of Ceramics for Sustainable Societal Development – International symposium in honor of Dr. Mrityunjay Singh

The proceedings papers from this conference are published in the below two issues of the 2018 CESP; Volume 39, Issues 2-3, as listed below.

CESP Volume 39, Issue 2: Includes 25 papers from Symposia 1, 2, 3, 4, 6, and 8
CESP Volume 39, Issue 3: Includes 22 papers from Symposia 9, 10, 12, 13, 14, 15, 16, FS1, The 7th GYIF, and the Dr. Mrityunjay Singh Honorary Symposium

The organization of the Daytona Beach meeting and the publication of these proceedings werw possible thankes to the professional staff of ACerS and the tireless dedicaion of many ECD members. We would especually like to express our sincere thanks to the symposia organizers, session chairs, presenters and conference attendees, for their efforts and enthusiastic participation in the vibrant and cutting-edge conference.

Valerie Wiesner, NASA Glenn Research Center, USA

Manabu Fukushima, National Institute of Advanced Industrial Science and Technology (AIST), japan

Volume Editors

August 2018